![]() Until recently, general rigid bead–rod theory has neglected interferences of the Stokes flow velocity profiles between nearby beads. In this way, how the shape of the macromolecule affects its rheological behavior in suspension is determined. Whereas beads represent points of Stokes flow resistances, the rods represent rigid separations. This theory sculpts macromolecules using beads and rods. When exploring how macromolecular architecture affects the elasticity of a polymeric liquid, we find the general rigid bead–rod theory to be both versatile and accurate. One good way to explain the elasticity of a polymeric liquid is to just consider the orientation distribution of the macromolecules.
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